Molecular vibrational trapping revisited: a case
نویسندگان
چکیده
This article presents a detailed study of the photodissociation probability of D 2 for a wide range of photon energy. One dimensional numerical calculations have been performed to provide the best possible physical quantities that characterize the vibrational trapping or bond hardening effect during the photodissociation dynamics. These results undoubtedly show that the nodes of the nuclear vibrational wave packets play a decisive role in the vibrational trapping, in addition to the current understating of this phenomenon.
منابع مشابه
Molecular vibrational trapping revisited: a case study with D2+
The present theoretical study is concerned with the vibrational trapping or bond hardening, which is a well-known phenomenon predicted by a dressed state representation of small molecules like and in an intense laser field. This phenomenon is associated with a condition where the energy of the light induced, vibrational level coincides with one of the vibrational levels on the field-free potent...
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